Interaction between Iron Fluoride and Molten FLiBe
نویسندگان
چکیده
The equilibrium potentials of iron in a LiF-BeF2-FeF2 melt were measured using the EMF method and dependent upon temperature fluoride concentrations. empirical equations for isotherms polytherms concentration obtained. cathode polarization molten mixture lithium beryllium was current switch off from stationary state. It found that studied ranges LiF-BeF2 electrolyte, valence state is mainly +2. According to experimental values electrode melt, conditional standard calculated relative reference fluoride. Gibbs energy change at formation difluoride element form dilute solutions, as thermodynamic (enthalpy entropy) when mixed with LiF-BeF2.
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ژورنال
عنوان ژورنال: Processes
سال: 2022
ISSN: ['2227-9717']
DOI: https://doi.org/10.3390/pr10122742